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Creators/Authors contains: "Reilly, Brendan_T"

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  1. Abstract Over the last 3.3 million years, the Antarctic Ice Sheet (AIS) has undergone phases of ice sheet growth and decay, impacting sea level and climate globally. Presently, the largely marine‐terminating AIS loses mass primarily by iceberg calving and basal melt of ice shelves. Quantifying past rates and timing of AIS melt is vital to understanding future cryosphere and sea level changes. One proxy for past ice sheet instabilities is iceberg rafted debris (IRD) fluxes. However, traditional methods of IRD quantification are labor‐intensive. Here, we present a new method of identifying IRD grains in sediment core X‐ray images using a convolutional neural network machine learning algorithm. We present a 3.3‐million‐year record of AIS IRD melt events using sediment cores from International Ocean Discovery Program Sites U1536, U1537, and U1538 in the Southern Ocean's “Iceberg Alley.” We identify two increases in the IRD fluxes throughout this period, at ∼1.8 and 0.43 Ma. We propose that after 1.8 Ma, the AIS expanded and transitioned from a primarily terrestrial‐terminating to a primarily marine‐terminating ice sheet. Therefore, after 1.8 Ma, glacial terminations and AIS iceberg discharge are associated with variations in global ice volume, presumably through the mechanism of sea level and, therefore, grounding line change. The second AIS regime change occurs during the Mid‐Brunhes Event (∼0.43 Ma). After this time, there are heightened and continuous IRD fluxes at each glacial termination, indicating increased AIS size and instability after this time. 
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  2. Abstract We document an apparent downward displacement of the Matuyama‐Brunhes magnetic reversal by ∼20 m at Scotia Sea International Ocean Discovery Program Site U1538 (Pirie Basin) by comparison with the well‐defined paleomagnetic record at nearby Site U1537 (Dove Basin). Detailed stratigraphic correlation between the two sites is possible due to similar lithologic variations. However, the two sites have distinctly different porewater geochemistry. Notably, Site U1538 indicates a greater demand for electron acceptors to oxidize organic carbon and Fe2+enrichment below the depth of SO42−depletion. Magnetic parameters indicate enrichment of an authigenic magnetic mineral with strong remanence properties around the depth of SO42−depletion (∼46 m at Site U1538) relative to magnetic parameters at correlative depths at Site U1537. Fe2+enrichment below the depth of SO42−depletion is not predicted based on the energetically favorable order of electron acceptors for microbial respiration but is documented here and in other depositional settings. This indicates Fe2+production exceeds the production of H2S by SO42−reduction, providing a geochemical environment that favors the production and preservation of ferrimagnetic remanence‐bearing iron sulfides over paramagnetic pyrite and, thus, a mechanism for deep chemical remanent magnetization acquisition at depths of tens of meters. The influence of authigenic ferrimagnetic iron sulfides on paleomagnetic signals can be difficult to demonstrate with magnetic properties alone; therefore, this finding has implications for evaluating the fidelity of magnetostratigraphic records with complementary geochemical data. Such situations should be considered in other depositional environments with similar porewater Fe2+accumulation below the SO42−reduction depth. 
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